catena-Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ2 O,O′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′] 4,4′-bipyridine disolvate monohydrate]
نویسندگان
چکیده
In the polymeric title complex, {[Ce(C(8)H(7)O(3))(3)(H(2)O)(2)]·2C(10)H(8)N(2)·H(2)O}(n), the Ce(III) ion is coordinated by ten O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and two water mol-ecules. One HPAA ligand coordinates just to one Ce(III) ion, whereas the remaining two bridge two Ce(III) ions. The 4,4'-bipyridine mol-ecule and one water mol-ecule are not coordinated to Ce. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds link mol-ecules into a three-dimensional network.
منابع مشابه
catena-Poly[[[diaqua(nitrato-κ2 O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′] monohydrate]
In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water mol-ecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, inter-molecular...
متن کاملBis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2 O,O′]ytterbium(III)} monohydrate
In the title dinuclear complex, [Yb(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Yb(III) atoms are coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal-prismatic geometry. Whereas four HPAA ligands coordinate to just two Yb(III) atoms, the re...
متن کاملBis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2 O,O′]dysprosium(III)} monohydrate
In the title dinuclear complex, [Dy(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, the Dy(III) atoms are coordinated by eight O atoms from four 2-(4-hy-droxy-phen-yl)acetate (HPAA) ligands and a water mol-ecule, and one N atom from a 4,4'-bipyridine (bipy) ligand in a distorted tricapped trigonal prismatic geometry. Whereas four HPAA ligands coordinate to just two Dy(III) atoms, the re...
متن کاملBis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ2 O,O′]samarium(III)} monohydrate
The dinuclear title complex, [Sm(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Sm(III) atoms, six deprotonated p-hy-droxy-phenyl-acetic acid (PAA) mol-ecules, two 4,4'-bipyridine (bipy) mol-ecules, two coordinated water mol-ecules and one solvent water molecule. Each Sm(III)ion is nine-coordinated by seven O atoms from four PAA ligands, one water O atom and one N atom fro...
متن کاملBis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua(4,4′-bipyridine-κN)[2-(4-hydroxyphenyl)acetato-κ2 O,O′]erbium(III)} monohydrate
The title dinuclear complex, [Er(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Er(III) atoms in the asymmetric unit, six 2-(4-hy-droxy-phen-yl)acetate (PAA) anions, two 4,4'-bipyridine (bipy) mol-ecules, two coordinated water mol-ecules and one solvent water mol-ecule. The central Er(III) atoms are nine-coordinated. The coordination environment includes six O atoms from t...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010